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 | Acesso ao texto completo restrito à biblioteca da Embrapa Instrumentação. Para informações adicionais entre em contato com cnpdia.biblioteca@embrapa.br. |
Registro Completo
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
25/04/2003 |
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Data da última atualização: |
25/04/2003 |
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Autoria: |
PATERNO, L. G.; MATTOSO, L. H. C. |
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Afiliação: |
UFSCar-Departaento de Engenharia de Materiais, São Carlos, SP; Embrapa Instrumentação Agropecuária, São Carlos, SP. |
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Título: |
Influence of different dopants on the adsorption, morphology, and properties of self-assembled films jof poly(o-ethoxyaniline). |
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Ano de publicação: |
2002 |
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Fonte/Imprenta: |
Journal of Applied Polymer Science, New York, v. 83, p. 1309-1316, 2002. |
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Idioma: |
Inglês |
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Conteúdo: |
Self-assembled films of poly(o-ethoxyaniline)-POEA alternated with sulfonated lignin (SL)-were sucessfully produced, and their kinetics of formation and growth investigated for different dopants (hydrochloric acid, methanesulfonic acid, p-toluenesulfonic acid, and camphosrsulfonic acid). These films were characterized by ultraviolet-visible spectroscopy, atomic force microscopy, surface potential, and electrical resistance measurements. It has been observed that the bulkiest dopants led to a greater time for the polymer deposition and greater abount of material adsorbed. This can be explained by the lower mobility and lower solvation of the bulkiest dopant counterions, which led to a higher screening effect of the charges present in the POEA chains and therefore to a more compact molecular conformation. The morphology of the POEA films were also gratly affected by the type of dopant used, being rougher for the bulkiest dopants. The POEA films also exhibited different electrical responses upon ethylene exposure depending on the dopant, indicating a promissing user for gas sensor applications. |
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Palavras-Chave: |
Derivatives; Dopant; Polyaniline; Self-assembly films. |
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Thesaurus NAL: |
adsorption. |
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Categoria do assunto: |
-- |
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Marc: |
LEADER 01708naa a2200193 a 4500
001 1024609
005 2003-04-25
008 2002 bl --- 0-- u #d
100 1 $aPATERNO, L. G.
245 $aInfluence of different dopants on the adsorption, morphology, and properties of self-assembled films jof poly(o-ethoxyaniline).
260 $c2002
520 $aSelf-assembled films of poly(o-ethoxyaniline)-POEA alternated with sulfonated lignin (SL)-were sucessfully produced, and their kinetics of formation and growth investigated for different dopants (hydrochloric acid, methanesulfonic acid, p-toluenesulfonic acid, and camphosrsulfonic acid). These films were characterized by ultraviolet-visible spectroscopy, atomic force microscopy, surface potential, and electrical resistance measurements. It has been observed that the bulkiest dopants led to a greater time for the polymer deposition and greater abount of material adsorbed. This can be explained by the lower mobility and lower solvation of the bulkiest dopant counterions, which led to a higher screening effect of the charges present in the POEA chains and therefore to a more compact molecular conformation. The morphology of the POEA films were also gratly affected by the type of dopant used, being rougher for the bulkiest dopants. The POEA films also exhibited different electrical responses upon ethylene exposure depending on the dopant, indicating a promissing user for gas sensor applications.
650 $aadsorption
653 $aDerivatives
653 $aDopant
653 $aPolyaniline
653 $aSelf-assembly films
700 1 $aMATTOSO, L. H. C.
773 $tJournal of Applied Polymer Science, New York$gv. 83, p. 1309-1316, 2002.
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